Last
update: 2019/4/20
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Kenta MOTOBAYASHI
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Research interests
Surface Science, Nanotechnology, and Electrochemistry
Current research topics
Structures and dynamics of
ionic liquid-electrode interfaces
Mechanistic studies of
electrochemical reactions in ionic liquids and in aqueous solutions
Previous research
Mechanism of heterogeneous
catalysis reactions: chirally modified metal particles, nano-porous gold and
etc.
-- Probing the orientation of chiral
modifiers that catalyzes the enantio-selective hydrogenation reactions.
Establishing single molecule vibrational spectroscopy
:
-- Development of curve
fitting analysis method for Action Spectroscopy using STM (Scanning Tunneling
Microscope).
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Structures, dynamics, and
vibrational properties of adsorbates :
-- Isolated water molecules and clusters on transition metal surfaces and etc.
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Energy dissipation process
and reaction mechanisms of single molecule reactions :
-- Dissociation of dimethyl disulfide on Cu(111) and etc.
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Education
2008-2011 : Department of Advanced Materials Science, The University of Tokyo
(Ph.D)
2006-2008 : Department of Advanced Materials Science, The University of Tokyo
(M.S.)
2002-2006 : Department of Applied Chemistry, The University of Tokyo (B.S.)
(Supervisor: Maki
Kawai)
Academic Position
2015- present
: Assistant Professor, Graduate School of Engineering, Nagoya Institute of
Technology
(2015-2016 : Visiting Associate Professor, Institute for Catalysis, Hokkaido
University)
(2011-2016 : Visiting Scientist, Surface and interface science laboratory,
RIKEN)
2011-2015 : Assistant Professor, Catalysis Research Center, Hokkaido University
2008-2011 : Research Fellow of the Japan Society for the Promotion of Science
(JSPS Research Fellow DC1)
Publications
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23 |
Electrochemical behavior of hydrophilic ionic liquid-water mixture |
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Sayuki Oka,
Makoto Chiba, Kenta Motobayashi,
and *Atsushi Hyono, |
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22 |
Potential-induced interfacial restructuring of a pyrrolidinium-based ionic liquid on an Au electrode: Effect of polarization of constituent ions |
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*Kenta Motobayashi, Yuhei Shibamura,
and Katsuyoshi Ikeda |
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21 |
Effect of the Side-Chain Structure of Perfluoro-Sulfonic Acid Ionomers on the Oxygen Reduction Reaction on the Surface of Pt |
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*Kenta Motobayashi and Masatoshi Osawa |
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20 |
Anharmonicity in a Double Hydrogen Transfer Reaction Studied in a Single Porphycene Molecule on a Cu(110) Surface |
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S. Liu, D.
Baugh, K. Motobayashi, X. Zhao, S.
V. Levchenko, S. Gawinkowski, J. Waluk, L. Grill, M. Persson, and *T. Kumagai |
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19 |
Effect of the Side-Chain Structure of Perfluoro-Sulfonic Acid Ionomers on the Oxygen Reduction Reaction on the Surface of Pt |
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*Kensaku
Kodama, Kenta Motobayashi, Akihiro
Shinohara, Naoki Hasegawa, Kenji Kudo, Ryousuke Jinnouchi, Masatoshi Osawa,
Yu Morimoto |
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18 |
Electrochemical THz-SERS Observation of Thiol Monolayers on Au(111) and (100) Using Nanoparticle-assisted Gap-Mode Plasmon Excitation |
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Motoharu
Inagaki, Kenta Motobayashi, and
*Katsuyoshi Ikeda |
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17 |
Potential-Induced Restructuring Dynamics of Ionic Liquids on a Gold Electrode: Steric Effect of Constituent Ions Studied by Surface-Enhanced Infrared Absorption Spectroscopy |
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Kenta Motobayashi, Naoya
Nishi, Yuki Inoue, Kazuya Minami, Tetsuo
Sakka, and Masatoshi Osawa |
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16 |
Interfacial
Structure at the Quaternary Ammonium-Based Ionic Liquids|Gold Electrode Interface Probed by Surface Enhanced Infrared Absorption Spectroscopy: Anion Dependence of the Cationic Behavior |
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Naoya Nishi,
Kazuya Minami, Kenta Motobayashi,
Masatoshi Osawa, and Tetsuo Sakka |
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15 |
Speciation of Adsorbed Phosphate at Gold Electrodes: A Combined Surface-Enhanced Infrared Absorption Spectroscopy and DFT Study |
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Momo
Yaguchi, Taro Uchida, Kenta
Motobayashi, and Masatoshi Osawa |
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14 |
Tracking a Common Surface-Bound Intermediate during CO2-to-Fuels Catalysis |
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Anna Wuttig,
Can Liu, Qiling Peng, Momo Yaguchi, Christopher H. Hendon, Kenta Motobayashi, Shen Ye, Masatoshi
Osawa, and Yogesh Surendranath |
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13 |
Inhibited Proton Transfer Enhances Au-Catalyzed CO2-to-Fuels Selectivity |
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Anna Wuttig,
Momo Yaguchi, Kenta Motobayashi, Masatoshi
Osawa, and Yogesh Surendranath |
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12 |
Potential-dependent Condensation of Water at the Interface between Ionic Liquid [BMIM][TFSA] and an Au Electrode |
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Kenta Motobayashi and
Masatoshi Osawa |
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11 |
Confinement of the Pt(111) Surface State in Graphene Nanoislands |
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Hyo Won Kim,
Seiji Takemoto, Emi Minamitani, Tomonari Okada, Takeshi Takami, Kenta Motobayashi, Michael Trenary,
Maki Kawai, Nobuhiko Kobayashi, and Yousoo Kim |
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10 |
The Role of Thermal Excitation in the Tunneling-Electron-Induced Reaction: Dissociation of Dimethyl Disulfide on Cu(111) |
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Kenta
Motobayashi, Yousoo Kim, Michiaki Ohara, Hiromu
Ueba, and Maki Kawai |
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9 |
Effect of Hydrogen on the Orientation of Cinchonidine Adsorbed on Platinum: An ATR-SEIRAS study |
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Kenta
Motobayashi, Ryota Tomioka, Taro Uchida, and
Masatoshi Osawa |
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8 |
Action Spectroscopy for Single-Molecule Reactions -Experiments and Theory |
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Yousoo Kim, Kenta
Motobayashi, Thomas Frederiksen, Hiromu Ueba, and Maki Kawai |
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7 |
Adsorption of Water Dimer on Platinum(111): Identification of the -OH···Pt Hydrogen Bond |
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Kenta
Motobayashi, Líney Árnadóttir, Chikako Matsumoto,
Eric M. Stuve, Hannes Jónsson, Yousoo Kim, and Maki Kawai |
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6 |
Dissociation pathways of a single dimethyl disulfide on Cu(111): Reaction induced by simultaneous excitation of two vibrational modes |
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Kenta
Motobayashi, Yousoo Kim, Ryuichi Arafune,
Michiaki Ohara, Hiromu Ueba, and Maki Kawai |
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5 |
Hysteresis of Potential-Dependent Changes in Ion Density and Structure of an Ionic Liquid on a Gold Electrode: In Situ Observation by Surface-Enhanced Infrared Absorption Spectroscopy |
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Kenta
Motobayashi, Kazuya Minami, Naoya Nishi, Tetsuo
Sakka, and Masatoshi Osawa |
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4 |
Spectral Fitting of Action Spectra for Motions and Reactions of Single Molecules on Metal Surfaces |
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Kenta
Motobayashi, Satoshi Katano, Yousoo Kim, and Maki
Kawai |
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3 |
Insight into Action Spectroscopy for Single Molecule Motion and Reactions through Inelastic Electron Tunneling |
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Kenta
Motobayashi, Yousoo Kim, Hiromu Ueba, and Maki
Kawai |
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Press
release (Japanese) |
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2 |
State-selective dissociation of a single water molecule on an ultrathin MgO film |
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Hyung-Joon
Shin, Jaehoon Jung, Kenta Motobayashi, Susumu Yanagisawa, Yoshitada Morikawa,
Yousoo Kim, and Maki Kawai |
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1 |
Vibrational study of water dimers on Pt(111) using a scanning tunneling microscope. |
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Kenta
Motobayashi, Chikako Matsumoto, Yousoo Kim and
Maki Kawai |
Publications in Japanese
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5 |
電極表面上のイオン液体の挙動が見えた |
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本林健太 |
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電極との界面におけるイオン液体の構造とその電位応答：表面増強赤外分光法による研究 (Structure and its Potential Dependence of Ionic Liquids on Electrode Surfaces: A Surface-Enhanced Infrared Study) |
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本林健太、西直哉、作花哲夫、大澤雅俊 (Kenta Motobayashi, Naoya Nishi, Tetsuo Sakka, and Masatoshi
Osawa) |
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3 |
STM を用いた単分子振動分光 (Single Molecule Vibrational Spectroscopy using STM) |
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川合真紀、金有洙、上羽弘、本林健太 (Maki Kawai, Yousoo Kim, Hiromu Ueba and Kenta Motobayashi) |
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STM を用いた表面吸着分子のアクションスペクトル―定量解析から得られる新知見― (Action Spectroscopy of Molecules Adsorbed on Metal Surfaces using STM: Insights Obtained from Quantitative Analysis) |
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本林健太、金有洙、上羽弘、川合眞紀 (Kenta Motobayashi, Yousoo Kim, Hiromu Ueba and Maki Kawai) |
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Pt(111）表面に吸着した水分子モノマーおよび ダイマーの表面ダイナミクス (Surface Dynamics of Water Monomers and Dimers on Pt(111) Surface) |
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本林健太、松本周子、金有洙、川合眞紀 (Kenta Motobayashi, Chikako Matsumoto, Yousoo Kim and Maki Kawai) |
Awards
2019 : |
Innovative Young Researcher Award, Nagoya Institute of Technology |
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2019 : |
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2018 : |
Innovative Young Researcher Award, Nagoya Institute of Technology |
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2017 : |
ISSS6,
Best Poster Award (8th International Symposium on Surface
Science) |
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2014 : |
5th
Meeting of Ionic Liquid Research Association (Japanese), Poster Award |
2010 : |
SSSJ,
student Award (The Surface Science Society of Japan) |
2009 : |
ICESS11,
Best Poster Award (11-th International Conference on
Electronic Spectroscopy and Structure) |
2007 : |
DIET
XI, Student Award (The Eleventh International workshop on
Desorption Induced by Electron Transition) |
Contact
Department of Engineering Physics, Electronics and Mechanics,
Graduate School of Engineering, Nagoya Institute of Technology
Gokisocho, Syowaku, Nagoya, Japan
+81(52)735-5496